Perovskite Nanostructures

perovskite_1    CsPbBr3 NW laser    Screen Shot 2017-03-21 at 11.25.51 PM    2D NS

Recently, there is a renaissance of halide perovskites as a class of semiconductor materials for a variety of photovoltaics and optoelectronics. Particularly, the inorganic halide perovskites draw more and more attention, owing to their enhanced stability toward moisture, oxygen, and heat, compared to the organic-inorganic hybrid perovskites (e.g. methylammonium lead iodide). The controlled synthesis, detailed structural analysis, optical, and electronic properties are of great fundamental interest. This project currently focuses on the synthesis of inorganic halide perovskite nanostructures and the characterization of their physical properties to 1) advance synthetic methodology of 0D, 1D, and 2D nanostructures, 2) establish and advance technology and instrumentation to study fundamental nanomaterial properties as well as the physical, chemical, and electronic interactions between them, and 3) apply the extracted knowledge to both develop integrated optoelectronic and photonic devices from these building blocks and to feed this knowledge back into the virtuous cycle of design, synthesis, measurement and application.

Research Milestones

  • 2015 – First atomically thin 2D perovskite: “Atomically Thin Two-Dimensional Organic-Inorganic Hybrid Perovskites”, L. Dou*, A. B. Wong*, Y. Yu*, M. Lai, N. Kornienko, S. W. Eaton, A. Fu, C. G. Bischak, J. Ma, T. Ding, N. S. Ginsberg, L. Wang, A. P. Alivisatos, and P. Yang, Science
  • 2015 – First CsPbX3 nanowires by colloidal synthesis: “Solution-phase Synthesis of Cesium Lead Halide Perovskite Nanowires”,Dandan Zhang, Samuel W Eaton, Yi Yu, Letian Dou, and Peidong Yang., J. Am. Chem. Soc.
  • 2015 – First perovskite nanorod vertical array: “Growth and Anion Exchange Conversion of CH3NH3PbX3 Nanorod Arrays for Light-Emitting Diodes”, Andrew Barnabas Wong, Minliang Lai, Samuel Wilson Eaton, Yi Yu, Elbert Lin, Letian Dou, Anthony Fu, and Peidong Yang, Nano Letters
  • 2016 – Atomic resolution TEM imaging of 2D perovskite: “Atomic Resolution Imaging of Halide Perovskites”,  Yi Yu*, Dandan Zhang*, Christian Kisielowski, Letian Dou, Nikolay Kornienko, Yehonadav Bekenstein, Andrew B Wong, A Paul Alivisatos, and Peidong Yang. Nano Letters
  • 2016 – Ultrathin CsPbBr3 nanowires: “Ultrathin Colloidal Cesium Lead Halide Perovskite Nanowires”, Dandan Zhang*, Yi Yu*, Yehonadav Bekenstein*, Andrew B Wong, A Paul Alivisatos, and Peidong Yang. J. Am. Chem. Soc.
  • 2016 – First CsPbX3 nanowire laser: “Lasing in Robust Cesium Lead Halide Perovskite Nanowires”,Samuel W Eaton, Minliang Lai, Natalie A Gibson, Andrew B Wong, Letian Dou, Jie Ma, Lin-Wang Wang, Stephen R Leone, and Peidong Yang, Proc. Natl. Acad. Sci. USA
  • 2017 – CsPbI3 nanowire phase transition: “Structural, optical, and electrical study of phase controlled cesium lead iodide nanowires”, Minliang Lai, Qiao Kong, Connor G. Bischak, Yi Yu, Letian Dou, Sam Eaton, Naomi S. Ginsberg, Peidong Yang, Nano Research
  • “Spatially Resolved Multi-Color CsPbX3 Nanowire Heterojunctions via Anion Exchange”, Letian Dou*, Minliang Lai*, Christopher S. Kley*, Yiming Yang, Connor G. Bischak, Dandan Zhang, Samuel W. Eaton, Naomi S. Ginsberg, and Peidong Yang. Proc. Natl. Acad. Sci. 114, 7216–7221 (2017). DOI: 10.1073/pnas.1703860114 [pdf]
  • “Ultralow thermal conductivity in all-inorganic halide perovskites”, Woochul Lee, Huashan Li,Andrew B. Wong, Dandan Zhang, Minliang Lai, Yi Yu, Qiao Kong, Elbert Lin, Jeffrey J. Urban, Jeffrey C. Grossman, and Peidong Yang. Proc. Natl. Acad. Sci.114, 8693–8697 (2017). DOI: 10.1073/pnas.1711744114 [pdf]
  • “Bandgap engineering in semiconductor alloy nanomaterials with widely tunable bandgaps and compositions”, Cun-Zheng Ning, Letian Dou and Peidong Yang. Nature Reviews Materials, 2, 1–15 (2017). DOI: 10.1038/natrevmats.2017.70 [pdf]
  • “Thermochromic Halide Perovskite Solar Cells”, Jia Lin*, Minliang Lai*, Letian Dou*, Christopher S. Kley, Hong Chen, Fei Peng, Junliang Sun, Dylan Lu, Steven A. Hawks, Chenlu Xie, Fan Cui, A. Paul Alivisatos, David T. Limmer, and Peidong Yang. Nature Mater., 17, 261–267 (2018). DOI: 10.1038/s41563-017-0006-0
  • “Electrical and Optical Tunability in All-Inorganic Halide Perovskite Alloy Nanowires”, Teng Lei, Minliang Lai, Qiao Kong, Dylan Lu, Woochul Lee, Letian Dou, Vincen Wu, Yi Yu, and Peidong Yang, Nano Lett., 18, 3538–3542 (2018). DOI: 10.1021/acs.nanolett.8b00603
  • “Phase transition induced p-n junction in single halide perovskite nanowire”, Qiao Kong, Woochul Lee, Minliang Lai, Connor G. Bischak, Guoping Gao, Andrew B. Wong, Teng Lei, Yi Yu, Lin-Wang Wang, Naomi S. Ginsberg, and Peidong Yang. Proc. Natl. Acad. Sci. USA, 3, 201806515–6 (2018).  DOI: 10.1073/pnas.1806515115.
  • “Intrinsic Anion Diffusivity in Lead Halide Perovskites is Facilitated by a Soft Lattice”, Minliang Lai*, Amael Obliger*, Dylan Lu, Christopher S. Kley , Connor G. Bischak , Qiao Kong, Teng Lei, Letian Dou, Naomi S. Ginsberg, David T. Limmer, and Peidong Yang. Proc. Natl. Acad. Sci. USA, 115, 11929–11934 (2018). DOI: 10.1073/pnas.1812718115.
  • “Giant Light-Emission Enhancement in Lead Halide Perovskites by Surface Oxygen Passivation” Dylan Lu, Ye Zhang, Minliang Lai, Alex Lee, Chenlu Xie, Jia Lin, Teng Lei , Zhenni Lin, Christopher S. Kley, Jianmei Huang, Eran Rabani, and Peidong Yang. Nano Lett., 18, 6967–6973 (2018). DOI: 10.1021/acs.nanolett.8b02887
  • “Quantitative imaging of anion exchange kinetics in halide perovskites”, Ye Zhang, Dylan Lu, Mengyu Gao, Minliang Lai, Jia Lin, Teng Lei, Zhenni Lin, Li Na Quan, and Peidong Yang. Proc Natl Acad Sci USA. 116, 12648–12653 (2019). DOI:10.1073/pnas.1903448116.
  • “Copper(I)-Based Highly Emissive All-Inorganic Rare-Earth Halide Clusters”, Jia Lin, Hong Chen, Jun Kang, Li Na Quan, Zhenni Lin, Qiao Kong, Minliang Lai, Sunmoon Yu, Lei Wang, Lin-wang Wang, Michael F. Toney and Peidong Yang, Matter, 1, 180–191 (2019). DOI: 10.1016/j.matt.2019.05.027.
  • “Self-Assembly of Two-Dimensional Perovskite Nanosheet Building Blocks into Ordered Ruddlesden–Popper Perovskite Phase”, Yong Liu, Martin Siron, Dylan Lu, Jingjing Yang, Roberto dos Reis, Fan Cui, Mengyu Gao, Minliang Lai, Jia Lin, Qiao Kong, Teng Lei, Joohoon Kang, Jianbo Jin, Jim Ciston, and Peidong Yang. J. Am. Chem. Soc. 141, 33, 13028-13032 (2019). DOI: 10.1021/jacs.9b06889.
  • “Pressure Induced Semiconductor to Metal Phase Transition of a Charge-Ordered Indium Halide Perovskite”, Jia Lin, Hong Chen, Yang Gao, Yao Cai, Jianbo Jin, Ahmed S. Etman, Joohoon Kang, Teng Lei, Zhenni Lin, Maria C. Folgueras, Li Na Quan, Qiao Kong, Matthew Sherburne, Mark Asta, Junliang Sun, Michael F. Toney, Junqiao Wu and Peidong Yang. Proc Natl Acad Sci USA. 116, 23404–23409 (2019). DOI: 10.1073/pnas.1907576116.
  • “Structural and spectral dynamics of single-crystalline Ruddlesden-Popper phase halide perovskite blue light-emitting diodes”, Hong Chen*, Jia Lin*, Joohoon Kang*, Qiao Kong, Dylan Lu, Jun Kang, Minliang Lai, Li Na Quan, Zhenni Lin, Jianbo Jin, Lin-wang Wang, Michael F. Toney and Peidong Yang. Science Advance, 6, eaay4045 (2020). DOI: 10.1126/sciadv.aay4045.
  • “Two-Dimensional Halide Perovskite Lateral Epitaxial Heterostructures”, Enzheng Shi, Biao Yuan, Stephen B. Shiring, Yao Gao, Akriti, Yunfan Guo, Cong Su, Minliang Lai, Peidong Yang, Jing Kong, Brett M. Savoie, Yi Yu, Letian Dou. Nature, 580, 614-620 (2020). DOI: 10.1038/s41586-020-2219-7.
  • “Scaling Laws of Exciton Recombination Kinetics in Low Dimensional Halide Perovskite Nanostructures”, Mengyu Gao, Hao Liu, Sunmoon Yu, Sheena Louisia, Ye Zhang, David P. Nenon, A. Paul Alivisatos and Peidong Yang. J. Am. Chem. Soc., 142, 8871-8879 (2020). DOI: 10.1021/jacs.0c02000.
  • “Lead-free Cesium Europium Halide Perovskite Nanocrystals”, Jianmei Huang, Teng Lei, Martin Siron, Ye Zhang, Sunmoon Yu, Fabian Seeler, Ahmad Dehestani, Li Na Quan, Kerstin Schierle-Arndt, Peidong Yang. Nano Letters, 20, 3734-3739 (2020). DOI: 10.1021/acs.nanolett.0c00692.
  • “Liquid-like Interfaces Mediate Structural Phase Transitions in Lead Halide Perovskites”, Connor G. Bischak, Minliang Lai, Zhaochuan Fan, Dylan Lu, Philippe David, Dengpan Dong, Hong Chen, Ahmed S. Etman, Teng Lei, Junliang Sun, Michael Grünwald, David T. Limmer, Peidong Yang, Naomi S. Ginsberg. Matter, 3, 534-545 (2020). DOI: 10.1016/j.matt.2020.07.015.
  • “Solid-state ionic rectification in perovskite nanowire heterostructures”, Qiao Kong, Amael Obliger, Minliang Lai, Mengyu Gao, David Limmer, Peidong Yang. Nano Letters, 20, 8151–8156 (2020). DOI: 10.1021/acs.nanolett.0c03204.
  • “Phase Transitions and Anion Exchange in All-Inorganic Halide Perovskites”, Julian A. Steele, Minliang Lai, Ye Zhang, Zhenni Lin, Johan Hofkens, Maarten B. J. Roeffaers, Peidong Yang. Acc. Mater. Res., 1, 3-15 (2020). DOI: 10.1021/accountsmr.0c00009.

 

Explore other research projects: